Devon Conway and Daryl Mitchell both scored unbeaten centuries, sharing a partnership of 180 runs.
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Ben Stokes marked his return to ODI cricket by scoring 52 runs.
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England's other top scorers were Dawid Malan (54) and Jos Buttler (72).
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Rachin Ravindra took 3-48 for New Zealand.
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New Zealand was always ahead of the run rate and batted with great tempo.
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Adil Rashid was the most expensive bowler for England, going for 1-70 in eight overs.
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Former England captain Andrew Flintoff was in Cardiff for the game.
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– The match was played at Sophia Gardens in Cardiff, Wales, England
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– The second ODI will be played in Southampton on Sunday.
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